Helium-argon isotopic tracing for the Pb-Zn-Ag polymetallic ore deposits in the central-south segment of the Da Hinggan Ling Range     

Baode Wang  Shuyin Niu  Aiqun Sun  Huabin Hu  Yaming Liu  Lijun Guo  Shuo Wang 《中国地球化学学报》2008,27(3):235-241

In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures.  相似文献   

江西金山金矿含金黄铁矿的Rb-Sr年龄   总被引：6，自引：0，他引：6  

毛光周  华仁民  高剑峰  龙光明  陆慧娟 《地球学报》2008,29(5):599-606

前人对江西金山金矿的成矿时代有许多不同的认识,笔者通过对江西金山蚀变岩型矿石中的含金黄铁矿Rb-Sr年龄的测定得出,含金黄铁矿的Rb-Sr等时线年龄为(838±110)Ma,initial87Sr/86Sr=0.7045±0.0020。由此可以推测晋宁期是蚀变岩型金矿体形成的主要时期。黄铁矿Rb-Sr所得的Sr同位素初始比(87Sr/86Sr)i小于陆源硅酸盐的值(0.720),而与玄武岩的值(0.704)接近,结合前人有关的同位素及稀土、微量元素研究,笔者认为金山金矿变质岩型矿体的成矿物质源于变质围岩,成矿流体为来源于深部的变质水。  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

Recommended Values of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry     

Taeko Shinonaga  Helmuth Aigner  Dilani Klose  Peter Spinder  Heinz Fröschl  David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.  相似文献   

The dynamics and thermodynamics of large ash flows   总被引：6，自引：6，他引：0  

Marcus I. Bursik  Andrew W. Woods 《Bulletin of Volcanology》1996,58(2-3):175-193

 Ash flow deposits, containing up to 1000 km³ of material, have been produced by some of the largest volcanic eruptions known. Ash flows propagate several tens of kilometres from their source vents, produce extensive blankets of ash and are able to surmount topographic barriers hundreds of metres high. We present and test a new model of the motion of such flows as they propagate over a near horizontal surface from a collapsing fountain above a volcanic vent. The model predicts that for a given eruption rate, either a slow (10–100 m/s) and deep (1000–3000 m) subcritical flow or a fast (100–200 m/s) and shallow (500–1000 m) supercritical flow may develop. Subcritical ash flows propagate with a nearly constant volume flux, whereas supercritical flows entrain air and become progressively more voluminous. The run-out distance of such ash flows is controlled largely by the mass of air mixed into the collapsing fountain, the degree of fragmentation and the associated rate of loss of material into an underlying concentrated depositional system, and the mass eruption rate. However, in supercritical flows, the continued entrainment of air exerts a further important control on the flow evolution. Model predictions show that the run-out distance decreases with the mass of air entrained into the flow. Also, the mass of ash which may ascend from the flow into a buoyant coignimbrite cloud increases as more air is entrained into the flow. As a result, supercritical ash flows typically have shorter runout distances and more ash is elutriated into the associated coignimbrite eruption columns. We also show that one-dimensional, channellized ash flows typically propagate further than their radially spreading counterparts. As a Plinian eruption proceeds, the erupted mass flux often increases, leading to column collapse and the formation of pumiceous ash flows. Near the critical conditions for eruption column collapse, the flows are shed from high fountains which entrain large quantities of air per unit mass. Our model suggests that this will lead to relatively short ash flows with much of the erupted material being elutriated into the coignimbrite column. However, if the mass flux subseqently increases, then less air per unit mass is entrained into the collapsing fountain, and progressively larger flows, which propagate further from the vent, will develop. Our model is consistent with observations of a number of pyroclastic flow deposits, including the 1912 eruption of Katmai and the 1991 eruption of Pinatubo. The model suggests that many extensive flow sheets were emplaced from eruptions with mass fluxes of 10⁹–10¹⁰ kg/s over periods of 10³–10⁵ s, and that some indicators of flow "mobility" may need to be reinterpreted. Furthermore, in accordance with observations, the model predicts that the coignimbrite eruption columns produced from such ash flows rose between 20 and 40 km. Received: 25 August 1995 / Accepted: 3 April 1996  相似文献   

Episode 49 of the Pu'u 'O'o-Kupaianaha eruption of Kilauea volcano-breakdown of a steady-state eruptive era     

M. T. Mangan  C. C. Heliker  T. N. Mattox  J. P. Kauahikaua  R. T. Helz 《Bulletin of Volcanology》1995,57(2):127-135

The Pu'u 'O'o-Kupaianaha eruption (1983-present) is the longest lived rift eruption of either Kilauea or neighboring Mauna Loa in recorded history. The initial fissure opening in January 1983 was followed by three years of episodic fire fountaining at the Pu'u 'O'o vent on Kilauea's east rift zone 19km from the summit (episodes 4–47). These spectacular events gave way in July 1986 to five and a half years of nearcontinuous, low-level effusion from the Kupaianaha vent, 3km to the cast (episode 48). A 49th episode began in November 1991 with the opening of a new fissure between Pu'u 'O'o and Kupaianaha. this three week long outburst heralded an era of more erratic eruptive behavior characterized by the shut down of Kupaianaha in February 1992 and subsequent intermittent eruption from vents on the west flank of Pu'u 'O'o (episodes 50 and 51). The events occurring over this period are due to progressive shrinkage of the rift-zone reservoir beneath the eruption site, and had limited impact on eruption temperatures and lava composition.  相似文献   

膜分离技术的应用及发展趋势   总被引：8，自引：0，他引：8  

岳志新  马东祝  赵丽娜  赵寒梅 《云南地理环境研究》2006,18(5):52-57

综述世界和中国膜分离技术的发展，并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍；并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用，并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素，膜分离技术将在人类社会的发展史上起到不可替代的作用。  相似文献   

Determination of total selenium in geological samples by HG-AFS？ After enrichment with thiol cotton fiber     

《中国地球化学学报》2006,25(B08):208-209

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Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia   总被引：1，自引：0，他引：1  

Saad A. Aiban   《Engineering Geology》2006,87(3-4):205-219

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.  相似文献   

Mixing and differentiation in the Oruanui rhyolitic magma, Taupo, New Zealand: evidence from volatiles and trace elements in melt inclusions     

Yang Liu  Alfred T. Anderson  Colin J. N. Wilson  Andrew M. Davis  Ian M. Steele 《Contributions to Mineralogy and Petrology》2006,151(1):71-87

Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km³ (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H₂O, CO₂ and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H₂O and CO₂ in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H₂O and CO₂ in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献